Polymeric methylene diphenyl diisocyanate

CAS No.

9016-87-9

Synonyms

PMDI; Polymethylene polyphenyl polyisocyanate; Polymeric MDI; also listed as Isocyanate (PMDI)

Molecular formula

Not applicable — polymeric or multi-component material

Molecular weight

Not specified in the supplied record.

Grade

Industrial grade

Packaging

Glass bottle with PTFE-lined closure / Steel drum
SKU FM-249 Category

Chemical Product Description & Applications

Polymeric MDI is an aromatic isocyanate mixture containing methylene diphenyl diisocyanate and higher-functionality homologues. Its NCO groups react with polyols to form polyurethane networks, while reaction with water can generate urea linkages and carbon dioxide. The mixture’s functionality supports rigid, highly connected structures and strong binding in appropriate industrial systems.

The selected material is general-purpose liquid PMDI, not pure monomeric MDI or a formulated polyol blend. It is used as the isocyanate component in foam manufacture and as a reactive binder in wood composites. In foams, catalysts, blowing systems and polyol structure establish cell development and rigidity. In wood products, the chemistry develops bonding within the lignocellulosic assembly during pressing.

Typical Applications

  • Rigid polyurethane and polyisocyanurate foams: Used as the isocyanate feedstock in formulated insulation-foam systems for boards, panels and other suitable constructions.
  • Engineered-wood binders: Used as a reactive binder in suitable oriented-strand board, particleboard and related wood-composite manufacturing processes.
  • Polyurethane adhesive and binder systems: Used in compatible moisture-reactive or two-component formulations where aromatic isocyanate chemistry develops the required bonded network.

Specifications

Parameter Specification Test Method
Appearance Clear colorless to brown liquid Visual inspection
Identification Consistent with authenticated reference FTIR fingerprint comparison
NCO content 30.5-32.0% w/w Dibutylamine back-titration
Viscosity at 25 C 150-300 mPa.s Rotational rheometer at 10 s-1
Acidity as HCl ≤0.05% w/w Potentiometric titration
Hydrolyzable chlorine ≤0.20% w/w Hydrolysis and argentometric titration

Specifications describe the standard grade. Tolerance, test method and documentation package are confirmed per order.

Documents & Handling

Packaging

Glass bottle with PTFE-lined closure / Steel drum

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