Tris(4-aminophenyl)amine
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Molecular formula
Molecular weight
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Chemical Product Description & Applications
Tris(4-aminophenyl)amine is a three-functional aromatic amine used as a branching node in polymer and porous-material synthesis. Its three primary amino groups participate in condensation or acylation, while the central triarylamine structure provides a conjugated, electron-rich core. This combines network-building functionality with a defined organic electronic motif.
The selected TAPA reagent is the free triamine rather than its nitro precursor or a preformed framework. Reaction with suitable aldehydes can create imine-linked networks, while suitable anhydride or acyl partners provide other polymer connections. The three-arm geometry influences network topology, but porosity and functional performance emerge from the complete monomer combination and synthesis. It is therefore a building block rather than a finished adsorbent.
Typical Applications
- Imine-linked covalent organic frameworks: Used as a trifunctional amine node with suitable aldehyde linkers to construct porous organic networks.
- Imide-containing porous polymers: Used with appropriate anhydride partners in network-forming condensation routes.
- Triphenylamine-based functional polymers: Used where reactive amino sites connect an electron-rich triarylamine core into a larger polymer architecture.
Specifications
| Parameter | Specification | Test Method |
|---|---|---|
| Appearance | Solid; color consistent with the reference sample | Visual inspection |
| Identification | Consistent with authenticated reference | FTIR fingerprint comparison |
| Chromatographic purity | ≥98.0 area% | HPLC with suitable UV or CAD detection |
| Total organic impurities | ≤2.0 area% | HPLC, area normalization |
| Largest individual impurity | ≤1.0 area% | HPLC, area normalization |
| Water | ≤1.0% w/w | Karl Fischer titration |
Specifications describe the standard grade. Tolerance, test method and documentation package are confirmed per order.
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