Poly(methylhydrosiloxane)
CAS No.
Synonyms
Molecular formula
Molecular weight
Not specified in the supplied record.
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Chemical Product Description & Applications
Polymethylhydrosiloxane is a silicone fluid carrying reactive silicon-hydrogen groups along a siloxane backbone. These Si-H groups react with suitable vinyl groups through catalyzed hydrosilylation, enabling network formation or attachment of organic functionality. The silicone structure also provides a basis for hydrophobic surface treatments after appropriate reaction and curing.
The selected material is a high-hydrogen methylhydrogen silicone fluid, not an inert dimethyl silicone oil. Its multiple Si-H sites allow it to act as a crosslinking component in addition-cure systems when matched with the vinyl-functional polymer. It can also be converted into modified silicones or used in formulated water-repellent treatments. Hydrogen functionality, rather than viscosity alone, determines its chemical contribution.
Typical Applications
- Addition-cure silicone elastomers: Used as an Si-H crosslinking component with suitable vinyl-functional silicones in catalyzed two-component or related curing systems.
- Textile and mineral water-repellent treatments: Used in appropriately formulated and cured surface treatments where reactive silicone deposits provide hydrophobic character.
- Organomodified silicone synthesis: Used as the reactive silicone backbone for hydrosilylation with suitable unsaturated compounds, producing silicone derivatives with modified interfacial properties.
Specifications
| Parameter | Specification | Test Method |
|---|---|---|
| Appearance | Clear colorless liquid | Visual inspection |
| Identification | Consistent with authenticated reference | FTIR fingerprint comparison |
| Hydrogen as Si-H | 1.50-1.65% w/w | Gas-volumetric active hydrogen determination |
| Kinematic viscosity at 25 C | 20-40 mm2/s | Capillary viscometry |
| Volatile matter | ≤2.0% w/w | Gravimetry, 150 C for 2 h |
| Density at 25 C | 0.99-1.01 g/cm3 | Oscillating U-tube densitometry |
Specifications describe the standard grade. Tolerance, test method and documentation package are confirmed per order.
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