Polymeric methylene diphenyl diisocyanate
CAS No.
Synonyms
Molecular formula
Molecular weight
Not specified in the supplied record.
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Chemical Product Description & Applications
Polymeric MDI is an aromatic isocyanate mixture containing methylene diphenyl diisocyanate and higher-functionality homologues. Its NCO groups react with polyols to form polyurethane networks, while reaction with water can generate urea linkages and carbon dioxide. The mixture’s functionality supports rigid, highly connected structures and strong binding in appropriate industrial systems.
The selected material is general-purpose liquid PMDI, not pure monomeric MDI or a formulated polyol blend. It is used as the isocyanate component in foam manufacture and as a reactive binder in wood composites. In foams, catalysts, blowing systems and polyol structure establish cell development and rigidity. In wood products, the chemistry develops bonding within the lignocellulosic assembly during pressing.
Typical Applications
- Rigid polyurethane and polyisocyanurate foams: Used as the isocyanate feedstock in formulated insulation-foam systems for boards, panels and other suitable constructions.
- Engineered-wood binders: Used as a reactive binder in suitable oriented-strand board, particleboard and related wood-composite manufacturing processes.
- Polyurethane adhesive and binder systems: Used in compatible moisture-reactive or two-component formulations where aromatic isocyanate chemistry develops the required bonded network.
Specifications
| Parameter | Specification | Test Method |
|---|---|---|
| Appearance | Clear colorless to brown liquid | Visual inspection |
| Identification | Consistent with authenticated reference | FTIR fingerprint comparison |
| NCO content | 30.5-32.0% w/w | Dibutylamine back-titration |
| Viscosity at 25 C | 150-300 mPa.s | Rotational rheometer at 10 s-1 |
| Acidity as HCl | ≤0.05% w/w | Potentiometric titration |
| Hydrolyzable chlorine | ≤0.20% w/w | Hydrolysis and argentometric titration |
Specifications describe the standard grade. Tolerance, test method and documentation package are confirmed per order.
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