Tris(4-aminophenyl)amine

CAS No.

5981-09-9

Synonyms

TAPA; 4,4′,4”-Triaminotriphenylamine

Molecular formula

C18H18N4

Molecular weight

290.37 g/mol

Grade

Reagent grade

Packaging

Aluminum foil laminate bag / Fiber drum with PE liner
SKU FM-269 Category

Chemical Product Description & Applications

Tris(4-aminophenyl)amine is a three-functional aromatic amine used as a branching node in polymer and porous-material synthesis. Its three primary amino groups participate in condensation or acylation, while the central triarylamine structure provides a conjugated, electron-rich core. This combines network-building functionality with a defined organic electronic motif.

The selected TAPA reagent is the free triamine rather than its nitro precursor or a preformed framework. Reaction with suitable aldehydes can create imine-linked networks, while suitable anhydride or acyl partners provide other polymer connections. The three-arm geometry influences network topology, but porosity and functional performance emerge from the complete monomer combination and synthesis. It is therefore a building block rather than a finished adsorbent.

Typical Applications

  • Imine-linked covalent organic frameworks: Used as a trifunctional amine node with suitable aldehyde linkers to construct porous organic networks.
  • Imide-containing porous polymers: Used with appropriate anhydride partners in network-forming condensation routes.
  • Triphenylamine-based functional polymers: Used where reactive amino sites connect an electron-rich triarylamine core into a larger polymer architecture.

Specifications

Parameter Specification Test Method
Appearance Solid; color consistent with the reference sample Visual inspection
Identification Consistent with authenticated reference FTIR fingerprint comparison
Chromatographic purity ≥98.0 area% HPLC with suitable UV or CAD detection
Total organic impurities ≤2.0 area% HPLC, area normalization
Largest individual impurity ≤1.0 area% HPLC, area normalization
Water ≤1.0% w/w Karl Fischer titration

Specifications describe the standard grade. Tolerance, test method and documentation package are confirmed per order.

Documents & Handling

Packaging

Aluminum foil laminate bag / Fiber drum with PE liner

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SDS

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