12-Hydroxystearic acid

CAS No.

106-14-9

Synonyms

12-HSA; 12-Hydroxyoctadecanoic acid; also listed as 12-Hydroxy Stearic Acid (12-HSA)

Molecular formula

C18H36O3

Molecular weight

300.48 g/mol

Grade

Industrial grade

Packaging

Sealed PE bag / PP woven bag with PE liner
SKU FM-247 Category

Chemical Product Description & Applications

12-Hydroxystearic acid is a saturated C18 fatty acid containing a secondary hydroxyl group. Its carboxyl group forms metal soaps, while the hydroxyl functionality promotes intermolecular association and structured thickening. This combination makes it an important starting material for lithium-soap greases and other rheology-building systems.

The selected industrial solid is the free fatty acid, not a preformed lithium soap or finished grease. Reaction with suitable metal bases produces soap thickeners that structure lubricating oils. It can also support organogel formation or further ester chemistry through its two different functional groups. The resulting texture and thermal response depend on the derivative formed, the oil phase and the manufacturing process.

Typical Applications

  • Lithium and lithium-complex greases: Used as a fatty-acid feedstock for producing lithium 12-hydroxystearate-based thickener systems in lubricating grease.
  • Metal-soap thickener manufacture: Used with suitable metal compounds to prepare hydroxystearate derivatives for industrial rheology and lubrication applications.
  • Organic-phase gelling formulations: Used in compatible systems where association of the hydroxy-fatty-acid structure helps build a network and reduce liquid flow.

Specifications

Parameter Specification Test Method
Appearance White to cream flakes Visual inspection
Identification Consistent with authenticated reference FTIR fingerprint comparison
Acid value 175-185 mg KOH/g Potentiometric titration
Hydroxyl value 155-165 mg KOH/g Acetylation and back-titration
Iodine value ≤3.0 g I2/100 g Wijs titration
Water ≤0.50% w/w Karl Fischer titration

Specifications describe the standard grade. Tolerance, test method and documentation package are confirmed per order.

Documents & Handling

Packaging

Sealed PE bag / PP woven bag with PE liner

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SDS

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