Sulfuryl chloride

CAS No.

7791-25-5

Synonyms

Sulphuryl chloride; Sulfuric oxychloride; Sulfonyl chloride

Molecular formula

SO2Cl2

Molecular weight

134.97 g/mol

Grade

Industrial grade

Packaging

Glass bottle with PTFE-lined closure / Steel drum
SKU FM-361 Category

Chemical Product Description & Applications

Sulfuryl chloride is a reactive inorganic liquid used as a chlorinating reagent in industrial organic synthesis. It supplies chlorine for conversion of selected aromatic and aliphatic substrates, including activated carbonyl compounds. It also has applications in oxidative chlorination of sulfur-containing intermediates, providing a second route to specialty chemical building blocks.

The formula SO2Cl2 distinguishes sulfuryl chloride from thionyl chloride, SOCl2. The liquid is moisture-reactive and is used in controlled dry chemical processing. Its function is established by the substrate and manufacturing route: aromatic chlorination, formation of chlorinated carbonyl intermediates and sulfur-intermediate conversion use different aspects of its reactivity. It is supplied as a concentrated reagent feedstock for further chemical conversion.

Typical Applications

  • Chlorinated aromatic intermediates: Used in manufacture of selected chlorophenol and related aromatic intermediates for specialty chemical and colorant production. It provides the chlorinating input in the established process.
  • Chlorinated carbonyl intermediates: Used in selected routes to alpha-chlorinated ketones and related carbonyl compounds. These intermediates supply defined structures for subsequent fine-chemical manufacture.
  • Specialty organosulfur intermediates: Used in compatible oxidative chlorination routes involving sulfur-containing substrates. The converted sulfur intermediates are used for further synthesis of specialty chemical products.

Specifications

Parameter Specification Test Method
Appearance Clear colorless to pale yellow liquid Visual inspection
Identification Consistent with authenticated reference FTIR fingerprint comparison
Assay ≥99.0% w/w Calibrated GC with moisture-free injection
Color ≤50 APHA Platinum-cobalt colorimetry
Nonvolatile residue ≤0.10% w/w Gravimetric residue under controlled conditions
Iron ≤10 mg/kg ICP-OES after controlled sample conversion

Specifications describe the standard grade. Tolerance, test method and documentation package are confirmed per order.

Documents & Handling

Packaging

Glass bottle with PTFE-lined closure / Steel drum

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CoA

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TDS

Technical Data Sheet

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SDS

Safety Data Sheet

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